|
Publications
|
|
||
| |
||
|
||
| ||
|
|
"Femtosecond photoisomerization of cis-azobenzene" T. Nägele, R. Hoche, W. Zinth, J. WachtveitlChem. Phys. Lett. 272 (1997) 489-495 Abstract: Femtosecond transient absorption measurements of the photoisomerization ofazobenzene excited at 435 nm in the long wavelength (npi*) band are presented. Forcis-azobenzene the experiments reveal an extremely fast photoproduct formation witha dominating 170 fs and a weak 2 ps component. During the decay of the excited statesome oscillatory features are found. Vibrational cooling of the hot photoproducts in theground state occurs on a time scale of ten picoseconds. A slower initial photoreaction,which can be described by two time constants, 0.32 ps and 2.1 ps, is found for thetrans-isomer. The experimental results support the idea, that excitation of the S1 (npi*)bands of azobenzene leads to photoisomerization via inversion at one of the nitrogenatoms. BMO authors (in alphabetic order): Randolf Hoche Thomas Nägele Josef Wachtveitl Wolfgang Zinth |
mailto: webmaster
Letzte Änderung: 2016-09-14 13:34
-------------------------------------------
nav.inc[abfrage], query:Delete from kurzzeitstatistik where TS<"1713623672"
-------------------------------------------
ERRNO: 0
-------------------------------------------
RESULT:
-------------------------------------------
ABORTED
-------------------------------------------
-------------------------------------------
nav.inc[abfrage], query:INSERT INTO kurzzeitstatistik (Datei, Adresse, id, TS) VALUES ("", "3.137.192.3" , "124" , "1713624272 " )
-------------------------------------------
ERRNO: 0
-------------------------------------------
RESULT:
-------------------------------------------
ABORTED
-------------------------------------------
-------------------------------------------
nav.inc[abfrage], query:INSERT INTO statistik (Datei, Adresse, id, TS, Laufzeit) VALUES ("", "3.137.192.3" , "124" , "1713624272 ","" )
-------------------------------------------
ERRNO: 0
-------------------------------------------
RESULT:
-------------------------------------------
ABORTED
-------------------------------------------