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Impressum
(c) 2002 BMO

"DABCO and DMAP - Why Are They Different in Organocatalysis?"
M. Baidya, S. Kobayashi, F. Brotzel, U. Schmidhammer, E. Riedle, and H. Mayr
Angewandte Chemie, Int. Ed. 46 , 6176 - 6179 (2007)
Angewandte Chemie 119, 6288 - 6292 (2007)


Abstract:
What makes a good organocatalyst?

DABCO (1,4-diazabicyclo[2.2.2]octane) is a thousandfold better nucleophile (k) and at the same time a million times better leaving group (k) than DMAP (4-(dimethylamino)pyridine). This apparent contradiction is resolved by consideration of the intrinsic reaction barriers.

BMO authors (in alphabetic order):
Eberhard Riedle
Uli Schmidhammer

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Letzte Änderung: 2016-09-14 13:34
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