BMOLogo
Publications

LMU München
Fakultät für Physik


Home

General
Research
Funding
Members
Publications
  All Publications
  PhD Theses
  Master Theses
  Search
  i Search
Lectures/Seminars
Conferences
Vacancies
Search

Internal




Impressum
(c) 2002 BMO

"Laboratory apparatus for the accurate, facile and rapid determination of visible light photoreaction quantum yields"
U. Megerle, R. Lechner, B. König, E. Riedle
Photochemical & Photobiological Sciences 9, 1400 - 1406 (2010)


Abstract:
A novel setup for the direct determination of the quantum yield in photocatalytic and photo-chemical processes is reported. It combines the opto-electronic measurement of the absorbed amount of light with established quantitative chemical analysis of the products. High power visible LEDs are found to be convenient light sources for the illumination without the need for spectral filtering. The LED output can be imaged efficiently and in a controlled fashion into the sample. The residual transmitted light is continuously monitored by a dedicated and calibrated solar cell. The setup can be used under the conditions of a chemical synthesis labo-ratory. All information needed for the assembly and operation of the device is made available. The performance is validated by comparison to standard chemical actinometry and by the de-termination of quantum yields for reactions reported by others and ones investigated in our own laboratory.

BMO authors (in alphabetic order):
Uwe Megerle
Eberhard Riedle

Order Hardcopy

WWW-Version

mailto: webmaster
Letzte Änderung: 2016-09-14 13:34