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"Slow Fluorescence and Fast Intersystem Crossing - The Xanthone Anomaly" B. Heinz, B. Schmidt, C. Root, F. Milota, B. Fierz, T. Kiefhaber, W. Zinth, P. GilchUltrafast Phenomena XV, Springer Series in Chem. Physics, Eds. Andrew M. Weiner and R. J. Dwayne Miller, Springer-Verlag, Berlin (2006) Abstract: Intersystem crossing of xanthone in protic solvents proceeds within ~ 1 ps, whereas its fluorescence decays within 60-600 ps. This is due to a delayed fluorescence from a 3npi* state energetically close to the 1pipi* state. BMO authors (in alphabetic order): Peter Gilch Bjoern Heinz Christopher Root Wolfgang Zinth Assoziierte Projekte: Ultrafast Intersystem Crossing in Aromatic Carbonyl Compounds |