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"Wavepacket Splitting in the First 100 fs Determines the Products from the Bond Cleavage of Diphenylmethylchloride" C. F. Sailer, N. Krebs, B. P. Fingerhut, R. de Vivie-Riedle, E. RiedleProceedings of the XVIIIth International Conference on Ultrafast Phenomena, Lausanne, Switzerland. EPJ Web of Conferences 41, 05042 (2013). Abstract: An elementary chemical reaction proceeds through two distinct conical intersections. Benzhydryl radicals are formed with a delay of 80 fs, cations after 125 fs. The optical signal increases more slowly due to planarization and solvation. BMO authors (in alphabetic order): Nils Krebs Eberhard Riedle Christian Sailer Order Hardcopy  WWW-Version |